Electric and Photocatalytic Properties of Graphene Oxide Depending on the Degree of Its Reduction

氧化石墨烯的电和光催化性能取决于其还原程度

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作者:László Péter Bakos, Lőrinc Sárvári, Krisztina László, János Mizsei, Zoltán Kónya, Gyula Halasi, Klára Hernádi, Anna Szabó, Dániel Berkesi, István Bakos, Imre Miklós Szilágyi

Abstract

When graphene oxide is reduced, the functional groups are released and the structure becomes more ordered. The degree of reduction might be tunable with the process parameters. In our work, graphene oxide is prepared and the effect of thermal and chemical reduction is investigated. The samples are characterized with TG/DTA-MS, SEM-EDX, TEM, XPS, ATR-FTIR, Raman spectroscopy and XRD. Their electrical resistance, cyclic voltammetry and photocatalytic activity data are investigated. The conductivity can be varied by several orders of magnitude, offering a tool to match its electrical properties to certain applications. Low temperature reduction in air offers a material with the highest capacitance, which might be used in supercapacitors. The bare graphene oxide has considerably larger photocatalytic activity than P25 TiO2. Reduction decreases the activity, meaning that reduced graphene oxide can be used as an electron sink in composite photocatalysts, but does not contribute to the photocatalytic activity by itself.

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