trans-Bis[2-(pyrimidin-2-yl)ethyn-yl]bis-(tri-phenylphosphine)palladium

反式-双[2-(嘧啶-2-基)乙炔基]双-(三苯基膦)钯

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Abstract

The title palladium complex, [Pd(C(6)H(3)N(2))(2)(C(18)H(15)P)(2)], was isolated as an impurity that co-eluted with the organic product of a palladium-catalyzed Sonogashira coupling. It crystallizes in the monoclinic space group C2/c with one half of the complex in the asymmetric unit. The palladium atom (site symmetry ) has a square-planar geometry with trans phosphine ligands. The P-Pd-C angle is 95.19 (9)°.

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