Abstract
The mol-ecular structure of the title compound, [Ag(NO(2))(C(21)H(21)P)(2)], exhibits a pseudo-tetra-hedral coordination around the central Ag(I) atom. The compound crystallizes with one mol-ecule in the asymmetric unit in the monoclinic space group P2(1)/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N inter-actions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.