(S,S)-Di-iodido-{3,3'-methyl-enebis[1-(1-hy-droxy-4-methyl-pentan-2-yl)imidazol-2-ylene]}palladium(II) ethanol monosolvate

(S,S)-二碘代-{3,3'-亚甲基-烯双[1-(1-羟基-4-甲基-戊-2-基)咪唑-2-亚基]}钯(II)乙醇单溶剂化物

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Abstract

The structure of the title solvated bis-N-heterocyclic carbene palladium(II) complex, [PdI(2)(C(19)H(32)N(4)O(2))(2)·C(2)H(6)O, exhibits a slightly distorted square-planar coord-in-ation at the palladium(II) atom, with the six-membered chelate ring adopting a boat conformation. One disordered ethanol solvent mol-ecule was co-crystallized. There are inter-molecular O-H⋯O hydrogen bonds in the structure. The chiral centers of the precursor imidazolium salt was preserved during the metalation process.

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