Radiative suppression of exciton-exciton annihilation in a two-dimensional semiconductor

二维半导体中激子-激子湮灭的辐射抑制

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Abstract

Two-dimensional (2D) semiconductors possess strongly bound excitons, opening novel opportunities for engineering light-matter interaction at the nanoscale. However, their in-plane confinement leads to large non-radiative exciton-exciton annihilation (EEA) processes, setting a fundamental limit for their photonic applications. In this work, we demonstrate suppression of EEA via enhancement of light-matter interaction in hybrid 2D semiconductor-dielectric nanophotonic platforms, by coupling excitons in WS(2) monolayers with optical Mie resonances in dielectric nanoantennas. The hybrid system reaches an intermediate light-matter coupling regime, with photoluminescence enhancement factors up to 10(2). Probing the exciton ultrafast dynamics reveal suppressed EEA for coupled excitons, even under high exciton densities >10(12) cm(-2). We extract EEA coefficients in the order of 10(-3), compared to 10(-2) for uncoupled monolayers, as well as a Purcell factor of 4.5. Our results highlight engineering the photonic environment as a route to achieve higher quantum efficiencies, for low-power hybrid devices, and larger exciton densities, towards strongly correlated excitonic phases in 2D semiconductors.

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