First example of an electropolymerizable heptazine bearing oligothiophene arms: a new way to produce well-defined heptazine-containing polymers

首个带有寡噻吩臂的可电聚合庚嗪实例:一种制备结构明确的含庚嗪聚合物的新方法

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Abstract

We prepared the first example of a heptazine molecule bearing three arms, each of them functionalized with a terminal thiophene. This novel molecule is strongly fluorescent, benefiting from the energy transfer between the strongly absorbing heptazine and strongly emitting benzothiadiazole-thiophene segments. This new molecule should enable multiple types of graftings by leveraging the various reactivities of the terminal thiophene moiety.

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