Competitive, substrate-dependent reductive debromination/dehydrobromination of 1,2-dibromides with triethylamine

1,2-二溴化物与三乙胺的竞争性、底物依赖性还原脱溴/脱溴化氢反应

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作者：McGraw,Kristen M,Kent,Greggory T,Gonzalez,Joseph R,Erden,Ihsan,Wu,Weiming
期刊：Tetrahedron Letters影响因子：1.500
时间：2017起止号：2017 May 17;58(20):1973-1975
doi：10.1016/j.tetlet.2017.04.024

Abstract

The interaction of various 1,2-dibromides with NEt(3) under various conditions (THF and DMF, respectively) at different temperatures was investigated. Our results from these reactions show that substrate dependent dehydrobrominations compete with reductive debrominations. A comprehensive discussion of these competitive pathways is offered.

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