Molecular Design of Sexiphenyl-Based Liquid Crystals: Towards Temperature-Stable, Nematic Phases with Enhanced Optical Properties

基于六苯基液晶的分子设计:迈向具有增强光学性能的温度稳定向列相

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Abstract

This research introduces a novel liquid crystal molecular design approach based on the para-sexiphenyl (6P) structure. Six new liquid crystalline materials were synthesized, incorporating an alkyl terminal and lateral substitutions of the sexiphenyl core to achieve temperature-stable and broad nematic phases. The synthetic pathway involved cross-coupling, resulting in derivatives with strong nematogenic characteristics. Optical investigations demonstrated that the tested material had high birefringence values, making it promising for optical and electronic applications. These results open up new avenues of research and offer potential practical applications in electronics, photonics, optoelectronics and beyond.

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