Abstract
Materials' plasmon activity is defined by their electronic structure. Nowadays, the application of plasmonic materials is increasingly determined by the possibilities to control the electronic processes in them. The electronic structure's design is of particular importance for tuning the plasmon frequency and the excitation of hot electrons, which are important parameters determining the interaction of the nanostructures with the environment. The effective control of these parameters is important for the improvement of the efficiency and sensitivity of various processes, diagnostic methods and technologies in the field of photocatalysis and surface enhancement spectroscopies. This review is focused on the characterization techniques and the approaches for tuning the electronic states of plasmonic media. The diversity of materials and their electronic structure determine the approach for the engineering of the electronic structure. In the case of noble metals, the possibility for tuning the energy for interband transitions from their d band is considered by using intermetallic alloys (between noble metals themselves and with an addition of post-transition metals in them), while in semiconductor materials-the effect of charge transfer is mainly used. Such knowledge is not only essential from a practical point of view, but also contributes to understanding the processes in the field of new materials such as 2D noble metals and intermetallics.