Abstract
In this experiment, NiCo(2)O(x) catalysts, with different elements added (Mg, Fe, Cu, and Ce), were prepared using the co-precipitation method to investigate their catalytic performance for carbon monoxide, as well as their water resistance and sulfur resistance. Combined with the sintering flue gas environment of Baosteel Zhanjiang Iron and Steel Co., Ltd., it provides a reference for the catalytic oxidation of CO in complex environments. The results reveal that the Fe-added catalysts exhibited a better CO catalytic performance and possessed good redox properties, and the Fe metal ion-added NiCo(2)O(x) catalysts showed a CO catalytic efficiency of 91.72% at 100 °C. Meanwhile, the Fe-added catalysts had the strongest resistance to water, with a conversion of 98.37% to CO at 140 °C, and with 10% water vapor. The Ce-added catalyst showed a better SO(2) resistance and hybrid resistance of SO(2) and H(2)O. Under the condition of sulfur addition, the CO conversion of the Ce-added catalyst was as high as 63.07% after 4 h of SO(2) introduction, and the efficiency could be restored to 100% after cutting off the supply of SO(2). Under the conditions of sulfur addition and water addition, the CO conversion of the catalyst was 98.23% after cutting off the SO(2).