Abstract
Ag-Zn alloys are identified as highly active and selective electrocatalysts for CO(2) reduction reaction (CO(2)RR), while how the phase composition of the alloy affects the catalytic performances has not been systematically studied yet. In this study, we fabricated a series of Ag-Zn alloy catalysts by magnetron co-sputtering and further explored their activity and selectivity towards CO(2) electroreduction in an aqueous KHCO(3) electrolyte. The different Ag-Zn alloys involve one or more phases of Ag, AgZn, Ag(5)Zn(8), AgZn(3,) and Zn. For all the catalysts, CO is the main product, likely due to the weak CO binding energy on the catalyst surface. The Ag(5)Zn(8) and AgZn(3) catalysts show a higher CO selectivity than that of pure Zn due to the synergistic effect of Ag and Zn, while the pure Ag catalyst exhibits the highest CO selectivity. Zn alloying improves the catalytic activity and reaction kinetics of CO(2)RR, and the AgZn(3) catalyst shows the highest apparent electrocatalytic activity. This work found that the activity and selectivity of CO(2)RR are highly dependent on the element concentrations and phase compositions, which is inspiring to explore Ag-Zn alloy catalysts with promising CO(2)RR properties.