Abstract
The use of solar photocatalysts to degrade organic pollutants is not only the most promising and efficient strategy to solve pollution problems today but also helps to alleviate the energy crisis. In this work, MoS(2)/SnS(2) heterogeneous structure catalysts were prepared by a facile hydrothermal method, and the microstructures and morphologies of these catalysts were investigated using XRD, SEM, TEM, BET, XPS and EIS. Eventually, the optimal synthesis conditions of the catalysts were obtained as 180 °C for 14 h, with the molar ratio of molybdenum to tin atoms being 2:1 and the acidity and alkalinity of the solution adjusted by hydrochloric acid. TEM images of the composite catalysts synthesized under these conditions clearly show that the lamellar SnS(2) grows on the surface of MoS(2) at a smaller size; high-resolution TEM images show lattice stripe distances of 0.68 nm and 0.30 nm for the (002) plane of MoS(2) and the (100) plane of SnS(2), respectively. Thus, in terms of microstructure, it is confirmed that the MoS(2) and SnS(2) in the composite catalyst form a tight heterogeneous structure. The degradation efficiency of the best composite catalyst for methylene blue (MB) was 83.0%, which was 8.3 times higher than that of pure MoS(2) and 16.6 times higher than that of pure SnS(2). After four cycles, the degradation efficiency of the catalyst was 74.7%, indicating a relatively stable catalytic performance. The increase in activity could be attributed to the improved visible light absorption, the increase in active sites introduced at the exposed edges of MoS(2) nanoparticles and the construction of heterojunctions opening up photogenerated carrier transfer pathways and effective charge separation and transfer. This unique heterostructure photocatalyst not only has excellent photocatalytic performance but also has good cycling stability, which provides a simple, convenient and low-cost method for the photocatalytic degradation of organic pollutants.