Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids

脂肪酸酯衍生物在1,1-二烷基和1,2,3-三烷基咪唑型离子液体中的复分解反应

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Abstract

The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6) (-), BF(4) (-) and NTf(2) (-)) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.

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