Abstract
Recently, emerging 2D material-supported metal single-atom catalysts (SACs) are receiving enormous attention in heterogeneous catalysis. Due to their well-defined, precisely located metal centers, unique metal-support interaction and identical coordination environment, these catalysts serve as excellent models for understanding the fundamental issues in catalysis as well as exhibiting intriguing practical applications. Understanding the correlations between metal-support combinations and the catalytic performance at the atomic level can be achieved on the SACs@2D materials nanoplatforms. Herein, recent advances of metal SACs on various types of 2D materials are reviewed, especially their exciting applications in the fields of chemicals, energy, and the environment. Based on the summary and perspectives, this work should contribute to the rational design of perfect metal SACs with versatile properties.