Preparation of interconnected tin oxide nanoparticles on multi-layered MXene for lithium storage anodes

在多层MXene上制备互连的氧化锡纳米颗粒用于锂离子存储负极

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Abstract

MXenes, a novel class of two-dimensional (2D) materials known for their excellent electronic conductivity and hydrophilicity, have emerged as promising candidates for lithium-ion battery anodes. This study presents a simple wet-chemical method for depositing interconnected SnO(2) nanoparticles (NPs) onto MXene sheets. The SnO(2) NPs act as both a high-capacity energy source and a spacer to prevent MXene sheets from restacking. The highly conductive MXene facilitates rapid electron and lithium-ion transport and mitigates the volume changes of SnO₂ during the lithiation/delithiation process by confining the SnO₂ NPs between the MXene layers. This composite anode, SnO(2)@MXene, leverages the high capacity of SnO(2) and the structural and mechanical stability MXene provides. The SnO(2)@MXene anode exhibits superior electrochemical performance, with a high specific capacity of 678 mAh g(- 1) at a current rate of 2.0 A g(- 1) over 500 cycles, outperforming pristine MXenes and SnO(2) nanoparticles.

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