Abstract
Mixtures of B(4)C, α-AlB(12) and B powders were reactively spark plasma sintered at 1800 °C. Crystalline and amorphous boron powders were used. Samples were tested for their impact behavior by the Split Hopkinson Pressure Bar method. When the ratio R = B(4)C/α-AlB(12) ≥ 1.3 for a constant B-amount, the major phase in the samples was the orthorhombic AlB(24)C(4), and when R < 1 the amount of AlB(24)C(4) significantly decreased. Predictions that AlB(24)C(4) has the best mechanical impact properties since it is the most compact and close to the ideal cubic packing among the Al-B-C phases containing B(12)-type icosahedra were partially confirmed. Namely, the highest values of the Vickers hardness (32.4 GPa), dynamic strength (1323 MPa), strain and toughness were determined for the samples with R = 1.3, i.e., for the samples with a high amount of AlB(24)C(4). However, the existence of a maximum, detectable especially in the dynamic strength vs. R, indicated the additional influence of the phases and the composite's microstructure in the samples. The type of boron does not influence the dependencies of the indicated mechanical parameters with R, but the curves are shifted to slightly higher values for the samples in which amorphous boron was used.