Abstract
Titanium disulfide (TiS(2)) is investigated as an advanced conversion electrode for sodium (Na)-ion batteries (NIB) in an ether-based electrolyte (NaPF(6)/glyme (DME)). The as-prepared TiS(2) demonstrates a high reversible capacity of 1040 mA h g(-1) at 0.2 A g(-1) with the capacity contribution of 521 mA h g(-1) in the voltage region below 1.0 V (vs Na/Na(+)), remarkable initial coulombic efficiency of 95.9% and superior rate capability of 621 mA h g(-1) at 40 A g(-1). The high conductivity of the Ti-based compounds and nanosized particles generated by chemical conversion reactions could minimize the entropic barrier for the reversible conversion, resulting in high reversibility and ultrafast charge/discharge ability of the electrode. Moreover, with its strong ability to adsorb soluble polysulfide intermediates, the as-prepared TiS(2) electrode exhibits superior cycling stability over 9000 cycles, serving as a stable and ultra-high capacity conversion electrode for NIBs.