Sepiolite-Supported Manganese Oxide as an Efficient Catalyst for Formaldehyde Oxidation: Performance and Mechanism

海泡石负载氧化锰作为高效甲醛氧化催化剂:性能与机理研究

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Abstract

The current study involved the preparation of a number of MnO(x)/Sep catalysts using the impregnation (MnO(x)/Sep-I), hydrothermal (MnO(x)/Sep-H), and precipitation (MnO(x)/Sep-P) methods. The MnO(x)/Sep catalysts that were produced were examined for their ability to catalytically oxidize formaldehyde (HCHO). Through the use of several technologies, including N(2) adsorption-desorption, XRD, FTIR, TEM, H(2)-TPR, O(2)-TPD, CO(2)-TPD, and XPS, the function of MnO(x) in HCHO elimination was examined. The MnO(x)/Sep-H combination was shown to have superior catalytic activities, outstanding cycle stability, and long-term activity. It was also able to perform complete HCHO conversion at 85 °C with a high GHSV of 6000 mL/(g·h) and 50% humidity. Large specific surface area and pore size, a widely dispersed active component, a high percentage of Mn(3+) species, and lattice oxygen concentration all suggested a potential reaction route for HCHO oxidation. This research produced a low-cost, highly effective catalyst for HCHO purification in indoor or industrial air environments.

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