Acetylene hydrochlorination over boron-doped Pd/HY zeolite catalysts

硼掺杂Pd/HY沸石催化剂上乙炔氢氯化反应

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Abstract

A novel boron-doped Pd/HY zeolite catalyst for acetylene hydrochlorination was prepared and exhibited an outstanding catalytic performance (the acetylene conversion was maintained at >95% for about 30 h). The boron species can stabilize catalytically active Pd(2+) species and weaken carbon deposition and Pd(2+) reduction during the reaction, thus improving the catalytic stability.

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