Synthesis of nano magnetic supported NHC-palladium and investigation of its applications as a catalyst in the Mizoroki-Heck cross-coupling reaction in H(2)O

纳米磁性负载NHC-钯的合成及其在H₂O中作为Mizoroki-Heck交叉偶联反应催化剂的应用研究

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Abstract

The unique properties of N-heterocyclic carbenes (NHCs) as an effective ligand for palladium catalytic centers have recently found much attention. In this work, Fe(3)O(4) nanoparticle supported palladium(II)-N-heterocyclic carbene catalyst was successfully designed, synthesized and characterized by various methods. The activity of the catalyst was evaluated in the Mizoroki-Heck cross-coupling reaction in which the desired products were obtained in high yield in H(2)O as a green solvent. The reaction was carried out in short reaction times using low amounts of the catalyst. Moreover, the catalyst was easily separated from the reaction media and reused for 5 cycles.

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