Abstract
Single crystals of two achiral and planar heterocyclic compounds, C(9)H(8)H(3)O(CA1) and C(8)H(5)NO(2) (CA4), recrystallized from ethanol, were characterized by single crystal X-ray analysis, respectively, and chiral crystallization was observed only for CA1 as P2(1)2(1)2(1) (# 19), whereas it was not observed for CA4P2(1)/c (# 14). In CA1, as a monohydrate, the hydrogen bonds were pronounced around the water of crystallization (O4), and the planar cyclic sites were arranged in parallel to slightly tilted positions. On the other hand, an anhydride CA4 formed a dimer by hydrogen bonds between adjacent molecules in the crystal, which were aggregated by van der Waals forces and placed in parallel planar cyclic sites.