Utilizing enantiomerically pure organic spacers for anion-centred clusters in a hybrid inorganic-organic lead-halide crystal

In this work, we present structural data of the novel, chiral material (S-2AH)(4)[Pb(2)Br(7)]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is based on the steric properties of the used enantiomerically pure precursors.