Abstract
A mononuclear complex [Dy(phenN(6))(HL')(2)]PF(6)·CH(2)Cl(2) (H(2)L' = R/S-1,1'-binaphthyl-2,2'-diphenol) with local D(6h) symmetry was synthesized. Structural determination shows that Dy(3+) was encapsulated within the coordination cavity of the neutral hexaaza macrocyclic ligand phenN(6), forming a non-planar coordination environment. The axial positions are occupied by two phenoxy groups of binaphthol in the trans form. The local geometry of Dy(3+) closely resembles a regular hexagonal bipyramid D(6h) configuration. The axial Dy-O(phenoxy) distances are 2.189(5) and 2.145(5) Å, respectively, while the Dy-N bond lengths in the equatorial plane are in the range of 2.524(7)-2.717(5) Å. The axial O(phthalmoxy)-Dy-O(phthalmoxy) bond angle is 162.91(17)°, which deviates from the ideal linearity. Under the excitation at 320 nm, the complex exhibits a characteristic emission peak at 360 nm, corresponding to the naphthalene ring. The AC susceptibility measurements under an applied DC field of 1800 Oe show distinct temperature-dependent and frequency-dependent AC magnetic susceptibility, typical of single-molecule magnetic behavior. The Cole-Cole plot in the temperature range of 6.0-28.0 K was fitted using a model incorporating Orbach and Raman relaxation mechanisms, giving an effective energy barrier of U(eff) = 300.2 K. Theoretical calculations on complex 1 reveal that the magnetization relaxation proceeds through the first excited Kramers doublets with a calculated magnetization blocking barrier of 404.1 cm(-1) (581.4 K).