Abstract
This study investigates the influence of dynamic perturbation on gelation behavior in a model colloidal system composed of hydrophobic silica particles dispersed in dioctyl phthalate. Contrary to the prevailing assumption that gelation is independent of oscillatory frequency, particularly at small strain amplitudes within the linear viscoelastic regime, our results reveal a pronounced dependence of gelation dynamics on the frequency of applied shear. In contrast, variations in strain amplitude and shear rate amplitude exert minimal effects. This observed behavior deviates significantly from classical gelation theory, which typically predicts frequency-independent rheological properties at the gel point. The results uncover a previously unrecognized viscoelastic phenomenon in soft colloidal materials, wherein microstructural rearrangements near the gelation threshold appear to be modulated by the timescale of mechanical excitation. As a result, traditional criteria for identifying gelation become less effective. The liquid-to-solid transition in these colloidal systems aligns more closely with the physics of particle jamming, rather than polymer network formation.