Abstract
Perovskite/organic tandem solar cells, as a next-generation high-efficiency photovoltaic technology, integrate the tunable bandgap characteristics of perovskite materials with the broad spectral absorption advantages of organic semiconductors, demonstrating remarkable potential to surpass the theoretical efficiency limits of single-junction cells, enhance device stability, and expand application scenarios. This architecture supports low-temperature solution processing and offers tunable bandgaps, lightweight flexibility, and ecofriendly advantages. This review systematically summarizes research progress in this field, with a primary focus on analyzing the working principles, performance optimization strategies, and key challenges of the technology. Firstly, the article discusses strategies such as defect passivation, crystallization control, and suppression of phase separation in wide-bandgap perovskite sub-cells, offering insights into mitigating open-circuit voltage losses. Secondly, for the narrow-bandgap organic sub-cells, this paper highlights the optimization strategies for both the active layer and interfacial layers, aiming to improve spectral utilization and enhance power conversion efficiency. Additionally, this paper emphasizes the optimization of optical transparency, electrical conductivity, and energy level alignment in the recombination layer, providing theoretical guidance for efficient current matching and carrier transport.