Rowlinson's concept of an effective hard sphere diameter

罗林森提出的有效硬球直径概念

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Abstract

Attention is drawn to John Rowlinson's idea that the repulsive portion of the intermolecular interaction may be replaced by a temperature-dependent hard sphere diameter. It is this approximation that made the development of perturbation theory possible for realistic fluids whose intermolecular interactions have a steep, but finite, repulsion at short separations.

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