Abstract
Oils and solvable organic pollutants in wastewater demand separations of the components along with efficient photocatalysis in water treatment. Herein, we report on a practical purification strategy by using the multifunctional nickel-dimethylglyoxime [Ni(DMG)(2)] microtubes to separate the liquid mixture and degrade organic pollutants. The self-assembled [Ni(DMG)(2)] tubes was synthesized by a facile co-precipitation method. The static contact angle of the film prepared by mixing [Ni(DMG)(2)] powder (1 : 2 wt%) into polydimethylsilicone (PDMS) to water can reach 161.3°, which can still remain superhydrophobic but oil-friendly under corrosion conditions. PDMS imparts good mechanical properties and serves as both the adhesive and hydrophobic material. PFOTS methanol solution contains a large number of low surface energy groups, which can reduce the surface free energy of [Ni(DMG)(2)] rough structure. The superhydrophobic rough surface prepared by hollow micron tubular [Ni(DMG)(2)] samples must have both low surface energy substance and hollow micron tubular morphology. Due to the unique wettability, oil and water were efficiently separated from the oil-water mixture through the films. The coated film itself is photocatalytic in degrading quinoline blue, rhodamine B, methyl orange and methylene blue. By using the film's multifunctionality, a practical wastewater treatment was realized via water-oil separation, followed by fast photocatalytic degradation of solvable dyes.