Abstract
Maleic anhydride (MAnh) and its derivatives comprise a collection of underutilized monomer classes, each with unique reactivities and properties, which afford the design and synthesis of highly functional (co)polymers. This review explores the opportunities and limitations associated with maleic anhydride and its derivatives in conventional radical and controlled radical polymerization techniques. The potential of these monomers to create (co)polymers with desirable properties in advanced polymer design is highlighted.