catena-Poly[[aqua-(2,2'-bipyridine-κN,N')copper(II)]-μ-5-nitro-isophthalato-κO,O:O]

链状聚合物[[水合-(2,2'-联吡啶-κN,N')铜(II)]-μ-5-硝基间苯二甲酸根-κO,O:O]

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Abstract

In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water mol-ecule and the chelating 2,2'-bipyridine ligands, are bridged by 5-nitro-benzene-1,3-dicarboxyl-ate dianions which act as tridentate ligands; the carboxyl-ate groups exhibit monodentate and symmetric bidentate coordination modes. The Cu(II) atoms show a strongly distorted octa-hedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O-H⋯O hydrogen bonds between coordinated water mol-ecules and carboxyl-ate groups.

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