Abstract
An Ag(I) dimer capped with labile organometallic diphosphorus ligands [Cp(2) Mo(2) (CO)(4) (η(2) -P(2) )] (Cp=C(5) H(5) ) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.