Abstract
Recent advancements in cultural heritage preservation have increasingly focused on the development and application of new composites, harnessing the diverse properties of their components. This study reviews the current state of research and practical applications of these innovative materials, emphasizing the use of inorganic phosphatic materials (in particular the hydroxyapatite) and various polymers. The compatibility of phosphatic materials with calcareous stones and the protective properties of polymers present a synergistic approach to addressing common deterioration mechanisms, such as salt crystallization, biological colonization, and mechanical weathering. By examining recent case studies and experimental results, this paper highlights the effectiveness, challenges, and future directions for these composites in cultural heritage conservation. The findings underscore the potential of these materials to enhance the durability and aesthetic integrity of heritage stones, promoting sustainable and long-term preservation solutions.