Abstract
Organosilicon polymers (silicones) are of enduring interest both as an established branch of polymer chemistry and as a segment of commercial products. Their unique properties were exploited in a wide range of everyday applications. However, current silicone trends in chemistry and materials engineering are focused on new smart applications, including stretchable electronics, wearable stress sensors, protective coatings, and soft robotics. Such applications require a fresh approach to methods for increasing the durability and mechanical strength of polysiloxanes, including crosslinked systems. The introduction of self-healing options to silicones has been recognized as a promising alternative in this field, but only carefully designed multifunctional systems operating with several different self-healing mechanisms can truly address the demands placed on such valuable materials. In this review, we summarized the progress of research efforts dedicated to the synthesis and applications of self-healing hybrid materials through multi-component systems that enable the design of functional silicon-based polymers for smart applications.