Abstract
In this study, three new 3D coordination polymers (CPs), {[Cd(3)(L)(H(2)O)(6)]·H(2)O}(n) (1), {[Cu(1.5)(L)(0.5)(bimb)(1.5)]·5H(2)O·DMF}(n) (2), and {[Mn(1.5)(H(3)L)(bibp)(0.5)(H(2)O)(2)]·3H(2)O}(n) (3) (bimb= 1,3-bis(imidazol-1-yl)benzene, bibp= 1,4-bis((4-imidazol-1-yl)benzyl)piperazine), were prepared under solvothermal or hydrothermal conditions based on a hexadentate ligand (1,3,5-triazine-2,4,6-triamine hexa-acetic acid (H(6)L)). Structural elucidations were carried out by IR spectra along with single-crystal X-ray diffraction analysis, while thermogravimetric analysis (TGA) (dynamic and isothermal) and XRD techniques were used for property evaluations of the polymers. Furthermore, the fluorescence properties and detection of the Fe(3+) ions in 1 were tested at room temperature, and the electrochemical behavior of 2 is also stated in this article.