Spectrophotometric methods for monitoring the microbial transformation of steroids. I. Determination of 9-alpha-fluorohydrocortisone and 9-alpha-fluoro-16-alpha-hydroxyhydrocortisone in fermentation broths

分光光度法监测类固醇的微生物转化。I. 发酵液中9α-氟氢化可的松和9α-氟-16α-羟基氢化可的松的测定

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Abstract

A method has been devised for the determination of 9alpha-fluorohydrocortisone and 9alpha-fluoro-16alpha-hydroxyhydrocortisone in fermentation broths. The method involves extraction of the two steroids from the broth with ethyl acetate, separation through the formation of the water-soluble borate complex of the vicinally hydroxylated steroid, and estimation of each steroid spectrophotometrically.

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