Abstract
The MAX phase represents a diverse class of nanolaminate materials with intriguing properties that have received incredible global research attention because they bridge the divide separating metals and ceramics. Despite the numerous potential applications of MAX phases, their complex structure leads to a scarcity of readily accessible pure MAX phases. As a result, in-depth research on synthesis methods, characteristics, and structure is frequently needed for appropriate application. This review provides a comprehensive understanding of the recent advancements and growth in MAX phases, focusing on their complex crystal structures, unique mechanical, thermal, electrical, crack healing, corrosion-resistant properties, as well as their synthesis methods and applications. The structure of MAX phases including single metal MAX, i-MAX and o-MAX was discussed. Moreover, recent advancements in understanding MAX phase behaviour under extreme conditions and their potential novel applications across various fields, including high-temperature coatings, energy storage, and electrical and thermal conductors, biomedical, nanocomposites, etc. were discussed. Moreover, the synthesis techniques, ranging from bottom-up to top-down methods are scrutinized for their efficacy in tailoring MAX phase properties. Furthermore, the review explores the challenges and opportunities associated with optimizing MAX phase materials for specific applications, such as enhancing their oxidation resistance, tuning their mechanical properties, and exploring their functionality in emerging technologies. Overall, this review aims to provide researchers and engineers with a comprehensive understanding of MAX phase materials and inspire further exploration into their versatile applications in materials science and engineering.