2-Amino-terephthalic acid N,N-dimethyl-formamide disolvate

2-氨基对苯二甲酸 N,N-二甲基甲酰胺二溶剂化物

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作者:Stefan Loos, Wilhelm Seichter, Edwin Weber, Florian Mertens

Abstract

The asymmetric unit of the title structure, C(8)H(7)NO(4)·2C(3)H(7)NO, contains one 2-amino-terephthalic acid and two N,N-dimethyl-formamide mol-ecules. Strong O-H⋯O hydrogen bonds between the acidic carb-oxy H atoms of 2-am-ino-terephthalic acid and the O atoms of both solvent mol-ecules form linear 1:2 complex units. One H atom of the amine group is involved in intra-molecular N-H⋯O hydrogen bonding, whereas the second one takes part in an inter-molecular N-H⋯O connection. Furthermore, the crystal is stabilized by weak C-H⋯O hydrogen bonds.

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