High-performance H(2)S gas sensor utilizing MXene/MoS(2) heterostructure synthesized via the Langmuir-Blodgett technique and chemical vapor deposition

利用Langmuir-Blodgett技术和化学气相沉积法合成的MXene/MoS₂异质结构制备高性能H₂S气体传感器

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Abstract

In this study, we developed an H(2)S gas sensor based on a MXene/MoS(2) heterostructure, using the Langmuir-Blodgett (LB) technique and chemical vapor deposition (CVD). Ti(3)C(2)T (x) MXene nanosheets were uniformly transferred onto SiO(2)/Si substrates via the LB technique, achieving near-complete coverage. Subsequently, flower-like MoS(2) was grown on the MXene-coated substrate through CVD, with vertical growth observed on the MXene layers. Our hybrid sensors exhibited a significant enhancement in gas response, with the MXene/MoS(2) heterostructure showing a response of 0.5 to H(2)S - approximately five times greater than that of pristine MXene. This improvement is attributed to the formation of a heterojunction, which increases electron mobility and reduces the depletion layer, enabling more efficient gas detection. Furthermore, the sensor demonstrated excellent selectivity for H(2)S over other gases, including H(2), NO(2), NH(3), NO, and VOCs. The combination of the LB technique and CVD not only enhances gas sensor performance but also offers a promising strategy for synthesizing materials for various electrochemical applications.

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