Adsorption Application of Choline Chloride Modified MIL-101 (Cr) in Carbon Capture and Storage

氯化胆碱改性MIL-101(Cr)在碳捕获与封存中的吸附应用

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Abstract

This study developed a new way of designing choline chloride-modified MOF-based materials with advanced gas adsorption properties. To design better carbon capture materials, MIL-101 (Cr) was prepared using the hydrothermal method, and then was modified with different concentrations of choline chloride in a one-step method to enhance its CO(2) adsorption capacity. The characterization and experimental results indicated that the modified ChCl-MIL-101(Cr) significantly enhanced the adsorption capacity for CO(2). Specifically, the 0.075-ChCl-MIL-101(Cr) showed a 61.191% increase in adsorption capacity compared to that of the raw material. Moreover, the regenerated adsorption loss rate of the modified material was below 4%, proving the permanence of the material synthesis. Simulating isotherms using Langmuir and Freundlich equations revealed the non-uniformity of surface bonding.

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