High adsorption to methylene blue based on Fe(3)O(4)-N-banana-peel biomass charcoal

基于Fe(3)O(4)-N-香蕉皮生物质炭对亚甲基蓝的高吸附性

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Abstract

This research focused on utilizing banana peel as the primary material for producing mesoporous biomass charcoal through one-step potassium hydroxide activation. Subsequently, the biomass charcoal underwent high-temperature calcination with varying impregnation ratios of KOH : BC for different durations in tubular furnaces set at different temperatures. The resultant biomass charcoal was then subjected to hydrothermal treatment with FeCl(3)·6H(2)O to produce biochar/iron oxide composites. The adsorption capabilities of these composites towards methylene blue (MB) were examined under various conditions, including pH (ranging from 3 to 12), temperature variations, and initial MB concentrations (ranging from 50 to 400 mg L(-1)). The adsorption behavior aligned with the Langmuir model and demonstrated quasi-secondary kinetics. After five adsorption cycles, the capacity decreased from 618.64 mg g(-1) to 497.18 mg g(-1), indicating considerable stability. Notably, Fe(3)O(4)-N-BC exhibited exceptional MB adsorption performance.

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