Synthesis of Hierarchical Porous Carbon in Molten Salt and Its Application for Dye Adsorption

熔盐中分级多孔碳的合成及其在染料吸附中的应用

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Abstract

Hierarchical porous carbon was successfully synthesized from glucose in a molten salt at 800 °C for 2 h. It was amorphous and contained numerous oxygen containing functional groups on its surface. The porous carbon with 1.0 wt% Fe(NO(3))(3)·9H(2)O oxidizing agent showed the highest specific surface area of 1078 m(2)/g, and the largest pore volume of 0.636 cm(3)/g, among all of the samples. Raman and TEM results revealed that it had more defects and pores than other as-prepared carbon materials. The adsorption capacities of as-prepared porous carbon for methylene blue (MB) and methyl orange (MO) were 506.8 mg/g and 683.8 mg/g, respectively. The adsorption isotherms fit the Langmuir model and the adsorption kinetics followed the pseudo-second-order kinetic model.

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