An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions

一种高效绿色离子液体,可用于抑制中性和碱性高盐模拟混凝土孔隙溶液中钢筋的腐蚀。

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Abstract

The effect of the green ionic liquid compound, Quaternium-32 (Q-32), on the corrosion inhibition performance of reinforcement steel, in a simulated concrete pore solution, was investigated at different temperatures and pH values, using electrochemical impedance spectroscopy (EIS). The inhibition efficiency was improved as the concentration of Q-32 and pH values were increased. However, it decreased as the temperature was raised. A Q-32 concentration of 20 µmol L(-1) exhibited a 94% inhibition efficiency at 20 °C. The adsorption isotherm was evaluated using EIS measurements, and it was found to obey the Langmuir isotherm. The surface topography was examined using an atomic force microscope and scanning electron microscope. The effect of the Q-32 concentration with the highest corrosion efficiency on the mechanical properties of the mortars was also explained by flexure and compression techniques.

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