Surface modifications of graphitic carbon nitride with metal particles and polymer blend as antibacterial and dye removal agents

以金属颗粒和聚合物混合物对石墨氮化碳进行表面改性,作为抗菌剂和染料去除剂

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Abstract

In this study, novel dual-function composite was developed to remove dye and inhibit the growth of bacteria. In short, a metal oxide zinc oxide particles (ZnOP), copper oxide particles (CuOP), nickel oxide particles (NiOP), and zinc/nickel/copper oxide particles (ZNC) which has the average size (obtained from FE-SEM) of 165.8 ± 31.1, 117.3 ± 36.0, 97.0 ± 29.3, 108.3 ± 73.4 nm, respectively was modified with a polymer blend (M8F), consisting of polyvinyl alcohol, chitosan, polyvinylpyrrolidone, polyethylene glycol and graphitic carbon nitride (g-C(3)N(4)). The composite that can inhibit the growth of Pseudomonas aeruginosa (PA) while can remove the most methylene blue (MB), malachite green (MG), and Congo red (CR) is ZNC/M8F/g-C(3)N(4). Additionally, ZnO/M8F/g-C(3)N(4) can be used as dual-function composite to remove methyl orange (MO) and inhibit the growth of Staphylococcus aureus (SA). In the case of Salmonella enterica (SE), none of the materials can inhibit at least 50% of the bacteria. Additionally, none of the materials can kill SA, PA, and SE. Hence, ZNC/M8F/g-C(3)N(4) and ZnO/M8F/g-C(3)N(4) must be further modified to remove all of the metioned dye and inhibit the growth of mentioned bacteria better. The dye removing and bacteria growth inhibition experiments were done using adsorption and minimum inhibition concentration method.

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