Abstract
There have been exciting developments in the field of polymer solar cells (PSCs) as the potential competitor to the traditional silicon-based solar cells in the past decades. The most successful PSCs are based on the bulk hetero-junction (BHJ) structure, which contains a bicontinuous nanoscale interpenetrating network of a conjugated polymer and a fullerene blend. The power conversion efficiencies (PCEs) of BHJ PSCs have now exceeded 11%. In this review, we present an overview of recent emerging developments of narrow bandgap conjugated polymers for PSCs. We focus on a few important acceptors used in the donor-acceptor type conjugated polymers for highly efficient PSCs. We also reviewed the emerged donor-π-acceptor (D-π-A) side chains polymers. The band-gaps and energy levels as well as the photovoltaic performances of conjugated polymers are discussed.