The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

基于水杨醛的氟化物传感器的奇特案例:化学传感器、化学剂量计,还是两者都不是?

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Abstract

Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1-3) based on (1)H-NMR, (19)F-NMR, LC-MS and UV-vis spectroscopy experiments.

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