Effect of CaSO(4) Incorporation on Pore Structure and Drying Shrinkage of Alkali-Activated Binders

CaSO₄掺入对碱激活胶凝材料孔隙结构和干燥收缩率的影响

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Abstract

This present study investigates the effects of CaSO(4) incorporation on the pore structure and drying shrinkage of alkali-activated slag and fly ash. The slag and fly ash were activated at a 5:5 ratio by weighing with a sodium silicate. Thereafter, 0%, 5%, 10%, and 15% of CaSO(4) were incorporated to investigate the changes in phase formation and internal pore structure. X-Ray Diffraction (XRD), thermogravimetry (TG)/derivative thermogravimetry (DTG), mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), and drying shrinkage tests were carried out to find the correlation between the pore structure and drying shrinkage of the specimens. The results showed that CaSO(4) incorporation increased the formation of thenardite, and these phase changes affected the pore structure of the activated fly ash and slag. The increase in the CaSO(4) content increased the pore distribution in the mesopore. As a result, the capillary tension and drying shrinkage decreased.

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