Abstract
Graphene oxide (GO) can dramatically enhance the gas separation performance of membrane technologies beyond the limits of conventional membrane materials in terms of both permeability and selectivity. Graphene oxide membranes can allow extremely high fluxes because of their ultimate thinness and unique layered structure. In addition, their high selectivity is due to the molecular sieving or diffusion effect resulting from their narrow pore size distribution or their unique surface chemistry. In the first part of this review, we briefly discuss different mechanisms of gas transport through membranes, with an emphasis on the proposed mechanisms for gas separation by GO membranes. In the second part, we review the methods for GO membrane preparation and characterization. In the third part, we provide a critical review of the literature on the application of different types of GO membranes for CO(2), H(2), and hydrocarbon separation. Finally, we provide recommendations for the development of high-performance GO membranes for gas separation applications.