Abstract
Covalent organic framework (COF) membranes have garnered significant attention in ion separation due to their high surface area, tunable pore size, excellent stability, and diverse functional groups. Over the past decade, various synthesis methods, such as solvothermal synthesis, interfacial synthesis, microwave-assisted solvothermal synthesis, and in situ growth, have been developed to fabricate COF membranes. COF membranes have demonstrated remarkable ion separation performance in different separation processes driven by pressure, electric field, and vapor pressure difference, showing great potential in a wide range of applications. Nevertheless, challenges in the synthesis and application of COF membranes still remain, requiring further research to fully realize their potential in ion separation. This review critically examines the development of COF membranes, from synthesis methods to ion separation applications. We evaluate the advantages and limitations of various synthesis techniques and systematically summarize COF membrane performance based on separation driving forces. Finally, we present a critical analysis of current challenges and offer perspectives on promising future research directions for advancing COF membrane technology in separation.