Large-Sized Nanocrystalline Ultrathin β-Ga(2)O(3) Membranes Fabricated by Surface Charge Lithography

利用表面电荷光刻技术制备大尺寸纳米晶超薄β-Ga(2)O(3)薄膜

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Abstract

Large-sized 2D semiconductor materials have gained significant attention for their fascinating properties in various applications. In this work, we demonstrate the fabrication of nanoperforated ultrathin β-Ga(2)O(3) membranes of a nanoscale thickness. The technological route includes the fabrication of GaN membranes using the Surface Charge Lithography (SCL) approach and subsequent thermal treatment in air at 900 °C in order to obtain β-Ga(2)O(3) membranes. The as-grown GaN membranes were discovered to be completely transformed into β-Ga(2)O(3), with the morphology evolving from a smooth topography to a nanoperforated surface consisting of nanograin structures. The oxidation mechanism of the membrane was investigated under different annealing conditions followed by XPS, AFM, Raman and TEM analyses.

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