Abstract
Graphene oxide (GO) was incorporated into polyamide-11 (PA11) via in-situ polymerization. The GO-PA11 nano-composite had elevated resistance to hydrolytic degradation. At a loading of 1 mg/g, GO to PA11, the accelerated aging equilibrium molecular weight of GO-PA11 was higher (33 and 34 kDa at 100 and 120 °C, respectively) compared to neat PA11 (23 and 24 kDa at 100 and 120 °C, respectively). Neat PA11 had hydrolysis rate constants (k(H)) of 2.8 and 12 (×10(-2) day(-1)) when aged at 100 and 120 °C, respectively, and re-polymerization rate constants (k(P)) of 5.0 and 23 (×10(-5) day(-1)), respectively. The higher equilibrium molecular weight for GO-PA11 loaded at 1 mg/g was the result of a decreased k(H), 1.8 and 4.5 (×10(-2) day(-1)), and an increased k(P), 10 and 17 (×10(-5) day(-1)) compared with neat PA11 at 100 and 120 °C, respectively. The decreased rate of degradation and resulting 40 % increased equilibrium molecular weight of GO-PA11 was attributed to the highly asymmetric planar GO nano-sheets that inhibited the molecular mobility of water and the polymer chain. The crystallinity of the polymer matrix was similarly affected by a reduction in chain mobility during annealing due to the GO nanoparticles' chemistry and highly asymmetric nano-planar sheet structure.