Fire Suppression and Thermal Behavior of Biobased Rigid Polyurethane Foam Filled with Biomass Incineration Waste Ash

生物质焚烧废灰填充的生物基硬质聚氨酯泡沫的灭火性能和热性能

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Abstract

Currently, there is great demand to implement circular economy principles and motivate producers of building materials to integrate into a closed loop supply chain system and improve sustainability of their end-product. Therefore, it is of great interest to replace conventional raw materials with inorganic or organic waste-based and filler-type additives to promote sustainability and the close loop chain. This article investigates the possibility of bottom waste incineration ash (WA) particles to be used as a flame retardant replacement to increase fire safety and thermal stability under higher temperatures. From 10 wt.% to 50 wt.% WA particles do not significantly deteriorate performance characteristics, such as compressive strength, thermal conductivity, and water absorption after 28 days of immersion, and at 32 °C WA particles improve the thermal stability of resultant PU foams. Furthermore, 50 wt.% WA particles reduce average heat release by 69% and CO(2) and CO yields during fire by 76% and 77%, respectively. Unfortunately, WA particles do not act as a smoke suppressant and do not reduce smoke release rate.

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